NiAl2O4 a promising catalyst in theory but limited in industrial scale

Moulia Hermione LOBOUE, Marcel SILUE

Résumé


NiAl2O4 is a particular type of spinel phase. This material is characterized by its stability in high temperature, chemical resistance, abrasion resistance and high hardness, and it is widely used due to its unique property. In the last few years many studies showed interest in heterogeneous catalysis: oxidation of NOX, and in steam reforming (production of Hydrogen, energy of the future). All these experiments showed very good catalytic results, at the laboratory scale. Till now, no catalyst instead of Ni/Al2O3 has been able to cross the line between laboratory and insdustrial scale: we will find no response in the paper mentionned above. Therefore this article try to explain us why this spinel supported or not couldn’t be use till now in industry,  through the problem which occur at the ivorian refinery in August 2008 due to the presence of NiAl2O4 in the steam reforming reactor.


Mots-clés


NiAl2O4; spinel phase; steam reforming; refinery

Texte intégral :

PDF

Références


Nancy N Zurita-Mendez1, Georgina Carbajal-De la Torre1, Erasmo Cadenas1, Hongbo Liu2 and Marco A Espinosa-Medina1, Materials Research Express, 6, 1, 2018

Nguyen Kim Nga, Dang Kim Chi, Synthesis, characterization and catalytic activity of CoAl2O4 and NiAl2O4 spinel-type oxides for selective catalytic reduction of NOx, Advances in Technology of Materials and Materials processing Journal, 6, N°2, 2010.

C.Ragupathia J. Judith Vijayaa, L.John Kennedy, Preparation, characterization and catalytic properties of nickel aluminate nanoparticles: A comparison between

conventional and microwave method, 21, 1, Journal of Saudi Chemical Society, 2016

Zawadzki M, Wrzyszcz J. Hydrothermal synthesis of nanoporous zinc aluminate with high surface area, 35,1, Mater. Res. Bull, 2000.

|5] Kinsley J J and Pederson L R. Material Research Society Symp Proc, 296, 1993.

Kaar D R and Sowman H G., Microcrystalline transition metal oxide spinel articles, US patent: 4757036, 1988.

Boucher B, Bhul R and Perrin M. Structures magnétiques et étude des propriétés magnétiques des spinelles cubiques NiMn2O4, Journal Phys Chem Solids, 31(2), 1970.

Sampath S K and Cordaro J F. Optical Properties of Zinc Aluminate, Zinc Gallate, and Zinc Aluminogallate Spinels, Journal of American Ceramic Society, 81(3), 1998.

|9] Siciliano P. Preparation, characterization and applications of thin films for gas sensors

prepared by cheap chemical method, Sens Actuators, B-70(1), 2000, 153-164.

Vijaya J J, Kennedy L J, Sekaran G and Nagaraja K S. Sol-gel derived (Sr, Ni) Al2O4 composites for benzene and toluene sensors, Material Letters, 61(30), 2007.

|11] Gilbert C A, Smith R, Kenny S D, Murphy S T, Grimes R W and Ball J A.

Spectroscopic manifestations of the Kondo effect on single adatoms, J. Phys Condens. Matter, 21(5), 2009.

Shixue D. Thermodynamic model for binary

aluminate systems, Journal Phys Chem, 85(25), 1981.

Sampath S K, Kanhere D G and Pandey R., Electronic structure of spinel oxides: zinc aluminate and zinc gallate, J. Phys Condens Matter, 11(18), 1999.

Ohgushi T and Umeno S. Low Temperature Synthesis of Dispersed Fine Particle of

Cobalt Aluminate-A New Application of Zeolite, Bulletin of Chemical Society Japan, 60 (12), 1987.

Murthy I A P S and Swamy C S. Catalytic behaviour of NiAl2O4 spinel upon hydrogen

treatment, Journal Mater Sci, 28(5), 1993.

Enger B C, Lodeng R, Walmsley J and Holmen A. Inactive aluminate spinels as precursors for design of CPO and reforming catalysts, Appl Catal A Gen, 383(1-2), 2010.

Kyoung Ho Song, Soon Kwan Jeong, Byung Hun Jeong, Kwan-Young Lee 1 and Hak Joo Kim, Effect of the Ni/Al Ratio on the Performance of NiAl2O4 Spinel-Based Catalysts for Supercritical Methylcyclohexane Catalytic Cracking, Catalyst, 11(3),2021

Taherian Z., Khataee Alireza.; Orooji Y., Facile synthesis of yttria-promoted nickel catalysts supported on MgO-MCM-41 for syngas production from green house gases. Renew. Sustain. Energy Rev., 134, 2020.

Taherian Z., Shahed Gharahshiran, V., Khataee, A.; Meshkani, F., Orooji, Y. Comparative study of modified Ni catalysts over mesoporous CaO-Al2O3 support for CO2/methane reforming. Catal. Commun.,

, 2020.

Jime C.; Boukha, Z.; Rivas, B.D., Gonza, J.R.; Gutie, J.I. Behavior of Coprecipitated NiAl2O4/Al2O3 Catalysts for Low-Temperature Methane Steam Reforming Energy Fuels 28, 2014.

Enger, B.C.; Lødeng, R.; Walmsley, J., Holmen, A. Inactive aluminate spinels as precursors for design of CPO and reforming catalysts. Appl. Catal. A Gen., 383, 2010

Ross, J.R.H.; Steel, M.C.F.; Zeini-Isfahani, A. Evidence for the participation of surface nickel, Journal of Catalysis, 52, 2, 1978

C.Ragupathia J. Judith Vijayaa, L.John Kennedy, Preparation, characterization and catalytic properties of nickel aluminate nanoparticles: A comparison between conventional and microwave method, Journal of Saudi Chemical Society, 21,1, 2017.

Nielson F. P. Ribeiro, Raimundo C.R., Netoa Silvia, F. Moya, Mariana M.V.M.Souza, Martin Schmal, Synthesis of NiAl2O4 with high surface area as precursor of Ni nanoparticles for hydrogen production, International Journal of Hydrogen Energy, 35, 21, 2010.

Lucia Blas, Patrick Dutournié, Sophie Dorge, Ludovic Josien, Damaris Kehrli, Arnold Lambert,

Thermal stability study of NiAl2O4 binders for Chemical Looping Combustion application, Fuel,

Volume 182, 15, 2016,

Elvia Leal, Laédna Souto Neiva, Jean Pierre La Martini Lima Sousa, Fábio Argolo, Heloysa Martins Carvalho Andrade, Ana Cristina, Figueiredo de Melo Costa, Lucianna Gama, Evaluation of Glycine Excess over NiAl2O4 Catalysts Prepared by Combustion Reaction for Steam Methane Reforming, Materials Science Forum, (660-661), 2010

Anna Krawczyńska-Piechna, Wojciech Kubissa,

Marcin Przedlacki, Krzysztof J. Wołosz, Synthesis and Characterization of Nickel Aluminate Spinel

(NiAl2O4) Prepared from the Equilibrium Mixture of Al2O3 and NiO, Applied Mechanics and Materials,

, 2015

Marziehossadat Shokrollahi, Yancheshmeh Ommolbanin, Alizadeh Sahraei Mustapha Aissaoui, Maria C.Iliuta, A novel synthesis of NiAl2O4 spinel from a Ni-Al mixed-metal alkoxide as a highly efficient catalyst for hydrogen production by glycerol

steam reforming, Applied Catalysis B: Environmental, 265, 2020

Alberto M. Becerra, Adolfo E. Castro-Luna, An investigation on the presence of NiAl2O4 in a stable Ni on Alumina catalyst for dry reforming, J. Chil. Chem. Soc., 50, N°2, 2005

Cristina Jiménez-González, Zouhair Boukha, Beatriz de Rivas, Juan Ramón González-Velasco,

Jose Ignacio, Gutiérrez-Ortiz Rubén, López-Fonseca,

Behaviour of nickel–alumina spinel (NiAl2O4) catalysts for isooctane steam reforming, International Journal of Hydrogen Energy, 40, Issue 15, 2015.

Didi Li, Yi Li, Xiaohui Liu, Yong Guo, Chih-Wen Pao, Jeng-Lung Chen, Yongfeng Hu, and Yanqin Wang, NiAl2O4 Spinel Supported Pt Catalyst: High Performance and Origin in Aqueous-Phase Reforming of Methanol, ACS Catal., 9, 10, 2019.

Dr. Lu Zhou, Dr. Lidong Li, Nini Wei, Jun Li, Prof. Jean-Marie Basset, Chem Cat Chem, Effect of NiAl2O4 Formation on Ni/Al2O3 Stability during Dry Reforming of Methane, vol 7, Issue 16, 2015

Patrick Littlewood, Shengsi Liu, Eric Weitz, Tobin J.Marks, Peter C.Stair, Ni-alumina dry reforming catalysts: Atomic layer deposition and the issue of Ni aluminate, 343, 1, 2020.

Kyoung Ho Song, Soon Kwan Jeong, Byung Hun Jeong, Kwan-Young Lee, Hak Joo Kim, Effect of the Ni/Al Ratio on the Performance of NiAl2O4 Spinel-Based Catalysts for Supercritical Methylcyclohexane

Catalytic Cracking, 11(3), 323, Catalysts 2021,

Thèse Boudjeloud Meriem, Préparation de catalyseurs à base de Nickel et application dans les réactions d'oxydation des alcanes légers (propane et méthane), université des sciences et de la technologie Houari Boumediene, 2021

Nguyen Kim Nga, Dang Kim Chi, Synthesis, characterization and catalytic activity of CoAl2O4 and NiAl2O4 spinel-type oxides for selective catalytic reduction of NOx, Advances in Technology of Materials and Materials processing Journal, 6, 2004.

Howard W.Turner, Anthony F.Volpe, Jr.W.H.Weinberg, High-throughput heterogeneous catalyst research, Surface Science, 603, 10–12, 2009

Carlos Ortega, Daria Otyuskaya, Erik-Jan Ras, Luis D. Virla, Gregory S. Patience, Hendrik Dathe, Experimental methods in chemical engineering: High Throughput Catalyst Testing — HTCT, The Canadian Journal of Chemical Engineering, 99, 2021

F. Auprètre, Claude Descormes, Daniel Duprez,

Le vaporeformage catalytique : un vieux procédé

pour une solution nouvelle, Piles à combustible et interface dans les transports, 2001

M. A. Fahim, T. A. Alsahhaf, et A. Elkilani,

« Introduction », in Fundamentals of Petroleum Refining, Elsevier, 2010, p. 1‑9.

INERIS, Les techniques de production de l’hydrogène et les risques associé, rapport d’étude, N° DRA-08-95313-07833B, 2008

M.Mbodji, Thèse, Conception et dimensionnement de réacteurs – échangeurs microstructures pour la production de garde synthèse par vaporeformage du méthane, Université de Lorraine, 2013.

V. Piemonte, Luisa Di Paola, Marcello De Falco, A Lulianelli, hydrogen production using inorganics membrane reactor, Advances in hydrogen production,

storage and distribution, 283-316, 2014.

B. Marcq, Thèse, Contribution à l’étude de l’environnement du nickel dans les verres silicatés, Université de Physique du globe de Paris, 2004.

R. Hyun-Seong, Jun Ki-Won, Back Seung-Chan,

Park Sang-Eon, Carbon Dioxide Reforming of Methane over Ni/ʘ-Al2O3 catalyst: effect of Ni content, Bull of the Korean Chem Soc., 23 N°8, 2002

N. Kim Nga et Dang Kim Chi, Synthesis Characterization and catalytic activity of CoAl2O4 and NiAl2O4 spinel – Types oxides of NOx selective reduction, J. of Material online, September 2005

O. Brandwoll, L.Kolbeisen, N. Olsen, O.Bolland,

Chemical looping combustion-reduction of nickel oxyde/nickel aluminate with hydrogen, Department

of Energy and process Engineering NTNU, Norway.

James T. Trichardson et, Robert Scates, Martin V Twigg, X-Ray Diffraction study of Nickel oxide reduction by hydrogen, Applied Catalysis A : General, 137-150, 2003.

Firuta Goga, A., Roxana Dudric, Liliana Bizo, Alexandra Avram, Thomas Dippong, Gabriel Katona,

Influence of the thermal treatment on the colour of RO.Al2O3 (R=Co ; Ni) type spinel pigments prepared by a modified sol-gel method, UBB chemia, 1, 2016

Meftah Nilda, Zeggaoui Lynda, Mémoire de Master, Etude des performances du four de steam reforming F201 de la section de production de gaz de synthèse au niveau du complexe pétrochimique CP1Z d’Arzew, Université M’Hamed


Renvois

  • Il n'y a présentement aucun renvoi.